Kakaretso: Bapisa khanyetso ea alkali, ho hlatsoa marang-rang, ho tlosoa ha oli le ts'ebetso ea ho tlosa boka ba mefuta e fapaneng ea li-surfactants tse fumanehang 'marakeng kajeno, ho kenyelletsa le lihlopha tse peli tse sebelisoang haholo tsa nonionic le anionic.
Lethathamo la khanyetso ea alkali ea li-surfactants tse fapaneng
Khanyetso ea alkali ea li-surfactants e na le likarolo tse peli. Ka lehlakoreng le leng, ke botsitso ba sebopeho sa lik'hemik'hale, se bonahalang haholo ka ho timetsoa ha liphatsa tsa lefutso tsa hydrophilic ka alkali e matla; ka lehlakoreng le leng, ho ke ke botsitso ba aggregation mmuso ka mokelikeli aqueous, e leng haholo-holo bonahatsoa ke phello letsoai hore senya solventization ea surfactant le etsa surfactant phaphametse kapa teba le ho arohana le metsi.
Mokhoa oa teko: Nka 10g/L ea surfactant, eketsa flake alkali, e behe mochesong o boletsoeng ka metsotso e 120 ebe u hlokomela, palo ea alkaline ha delamination kapa bleaching ea oli e etsahala ke boholo ba ho hanyetsa alkaline.
Tafole e latelang e bonts'a khanyetso ea alkali ea li-surfactants tse tloaelehileng tse fumanehang hajoale.
Lebitso la surfactant | 40 ℃ | 70 ℃ | 100 ℃ |
AEO-5 | Sodium hydroxide 15 g/L | Sodium hydroxide 13 g/L | Sodium hydroxide 3g/L |
AEO-7 | Sodium hydroxide 22 g/L | Sodium hydroxide 14 g/L | Sodium hydroxide 5g/L |
AEO-9 | Sodium hydroxide 30 g/L | Sodium hydroxide 24 g/L | Sodium hydroxide 12g/L |
TX-10 | Sodium hydroxide 19 g/L | Sodium hydroxide 15 g/L | Sodium hydroxide 6g/L |
OP-10 | Sodium hydroxide 27 g/L | Sodium hydroxide 22 g/L | Sodium hydroxide 11 g/L |
Moemeli ea phunyeletsang JFC | Sodium hydroxide 21 g/L | Sodium hydroxide 16 g/L | Sodium hydroxide 9g/L |
Fast T e phunyeletsa | Sodium hydroxide 10 g/L | Sodium hydroxide 7 g/L | Sodium hydroxide 3g/L |
Sesepa sa Net 209 | Sodium hydroxide 18 g/L | Sodium hydroxide 13 g/L | Sodium hydroxide 5g/L |
EL-80 | Sodium hydroxide 29 g/L | Sodium hydroxide 22 g/L | Sodium hydroxide 8 g/L |
Har'a 80 | Sodium hydroxide 22 g/L | Sodium hydroxide 11 g/L | Sodium hydroxide 7 g/L |
Lilemo tse 80 | Sodium hydroxide 14 g/L | Sodium hydroxide 13 g/L | Sodium hydroxide 5 g/L |
Sodium dodecylbenzene sulfonate LAS | Sodium hydroxide 24 g/L | Sodium hydroxide 16 g/L | Sodium hydroxide 9g/L |
Sodium dodecyl sulfate SDS | Sodium hydroxide 81 g/L | Sodium hydroxide 44 g/L | Sodium hydroxide 15g/L |
Sodium ea bobeli alkyl sulfonate SAS | Sodium hydroxide 30 g/L | Sodium hydroxide 22 g/L | Sodium hydroxide 12g/L |
Sodium decyl-sulfonate AOS | Sodium hydroxide 29 g/L | Sodium hydroxide 20 g/L | Sodium hydroxide 13 g/L |
Coconut fatty acid diethanolamide | Sodium hydroxide 18 g/L | Sodium hydroxide 8 g/L | Sodium hydroxide 3 g/L |
Mafura a joala a ether sulfate AES | Sodium hydroxide 98 g/L | Sodium hydroxide 77 g/L | Sodium hydroxide 35g/L |
Mafura a joala ether carboxylate AEC | Sodium hydroxide 111 g/L | Sodium hydroxide 79 g/L | Sodium hydroxide 40g/L |
Clotrimazole(mokelikeli) | Sodium hydroxide 145 g/L | Sodium hydroxide 95 g/L | Sodium hydroxide 60g/L |
Phosphate ea lino tse tahang tse mafura | Sodium hydroxide 180 g/L | Sodium hydroxide 135 g/L | Sodium hydroxide 110g/L |
Phosphate esters ea mafura a joala ethers | Sodium hydroxide 210 g/L | Sodium hydroxide 147 g/L | Sodium hydroxide 170g/L |
Lethathamo la ts'ebetso ea ho hlatsoa nete ea surfactant
U sebelisa thepa e le 'ngoe e tala, ho latela maemo a naha a GB13174-2003 bakeng sa detergency ea sesepa sa ho hlatsoetsa liaparo, leka lisebelisoa tsa ho hlatsoa letlooa la lisebelisoa tse fapaneng ka tsela e latelang: lokisa lisebelisoa tse tala ka metsi a thata a 250ppm ho fumana tharollo ea 15% ea lisebelisoa tse tala. , hlatsoa ho latela GB/T 13174-2003 "detergency washing test method", lekanya bosoeu ba masela a fapaneng a silafetseng pele le ka mor'a ho hlatsoa, 'me u bale boleng ba detergency R ho latela foromo e latelang:
R(%)=F2-F1
Moo F1 e leng boleng ba bosoeu ba pele ho hlatsuoa ba lesela le silafetseng (%), F2 ke boleng ba bosoeu ba ka morao ho hlatsuoa ba lesela le silafetseng (%).
Ha boleng ba R bo le boholo, matla a ho hlatsoa letlooa a matlafala. Tekanyetso ena ea teko e ka sebelisoa ho tšoaea ho tlosoa ha litšila ka kakaretso ke li-surfactants 'me ha e sebetse ho bonahatsa bokhoni ba ho tlosa mafura le boka.
Lebitso la surfactant | R (%) boleng |
AEO-3 | R (% = 3.69 |
AEO-5 | R (% = 3.31 |
AEO-7 | R (% = 9.50 |
AEO-9 | R (% = 12.19 |
TX-10 | R (% = 15.77 |
NP-8.6 | R (% = 14.98 |
OP-10 | R (%)=14.55 |
XL-90 | R (% = 13.91 |
XP-90 | R (%)=4.30 |
HO YA-90 | R (%)=15.58 |
Penetrant JFC | R (% = 2.01 |
Fast T e phunyeletsa | R (% = 0.77 |
Sesepa sa Net 209 | R (% = 4.98 |
Sodium dodecylbenzene sulfonate LAS | R (% = 9.12 |
Sodium dodecyl sulfate SDS | R (% = 5.30 |
Sodium decyl-sulfonate AOS | R (% = 8.63 |
Sodium ea bobeli alkyl sulfonate SAS | R (%)=15.81 |
Mafura a joala a ether sulfate AES | R (% = 5.91 |
Mafura a joala ether carboxylate AEC | R (%)=6.20 |
Clotrimazole(mokelikeli) | R (%)=15.55 |
Phosphate ea lino tse tahang tse mafura | R (% = 2.08 |
Phosphate esters ea mafura a joala ethers AEP | R (% = 5.88 |
Papiso ea ts'ebetso ea ho tlosa oli ea li-surfactants tse fapaneng
Teko ea ho tlosa oli ea surfactant (mokhoa oa sekhahla sa ho tlosa oli) e etsoa ho latela GB 9985-2000 Sehlomathiso sa B, ho sebelisoa sesepa se tloaelehileng e le foromo e tloaelehileng. Bala sekhahla sa ho tlosoa ha oli (C) ho latela foromo e latelang:
C = boleng ba ho tlosa oli ea sampole / boleng ba ho tlosa oli ea sebopeho se tloaelehileng
Ha boleng ba C bo le boholo, bo matlafatsa bokhoni ba ho tlosa oli ea sebatli
Lebitso la surfactant | De-oiling C boleng |
AEO-3 | Ho tlotsa oli boleng ba C=1.53 |
AEO-5 | Theko ea ho tlosa oli ea C=1.40 |
AEO-7 | Theko ea ho tlosa oli ea C=1.22 |
AEO-9 | Theko ea ho tlosa oli ea C=1.01 |
TX-10 | Theko ea ho tlosa oli ea C=1.17 |
NP-8.6 | Theko ea ho tlosa oli ea C=1.25 |
OP-10 | Ho tlotsa oli boleng ba C=1.37 |
XL-90 | Theko ea ho tlosa oli ea C=1.10 |
XP-90 | Ho tlotsa oli boleng ba C=0.66 |
HO YA-90 | Theko ea ho tlosa oli ea C=1.40 |
Hlakola JFC | Theko ea ho tlosa oli ea C=0.77 |
Mafura a mafura a methyl ester ethoxylate FMEE | Ho tlotsa oli boleng ba C=1.94 |
Fast T e phunyeletsa | Ho tlotsa oli boleng ba C=0.35 |
Sesepa sa Net 209 | Theko ea ho tlosa oli ea C=0.76 |
Sodium dodecylbenzene sulfonate LAS | Ho tlotsa oli boleng ba C=0.92 |
Sodium dodecyl sulfate SDS | Theko ea ho tlosa oli ea C=0.81 |
Sodium decyl-sulfonate - AOS | Theko ea ho tlosa oli ea C=0.73 |
Sodium ea bobeli alkyl sulfonate SAS | Theko ea ho tlosa oli ea C=0.98 |
Mafura a joala a ether sulfate AES | Ho tlotsa oli boleng ba C=0.63 |
Mafura a joala ether carboxylate AEC | Theko ea ho tlosa oli ea C=0.72 |
Clotrimazole(mokelikeli) | Theko ea ho tlosa oli ea C=1.11 |
Phosphate ea lino tse tahang tse mafura | Ho tlotsa oli boleng ba C=0.32 |
Phosphate esters ea mafura a joala ethers AEP | Ho tlotsa oli boleng ba C=0.46 |
Tafole ea papiso ea ts'ebetso ea ho tlosa boka bo holimo
1. Tokisetso ea lesela le tloaelehileng la boka
Hlakola boka ba bokae bo tloaelehileng ho likhato tse 90 tsa metsi a chesang, hlohlelletsa hantle 'me u bo qoelise ka har'a lesela le tloaelehileng la ho hlatsoa le lesoeu, le tlose ka mor'a metsotso e' meli 'me u omelle moea.
2. Mokhoa oa teko
Lesela la boka le khaotsoe ka 5 * 5cm, le qoelisoa ka mokelikeli o sebetsang ka 5% ea lihlahisoa tse tala, li hlatsuoa ka oscillation ka metsotso e 10 tlas'a mocheso oa mocheso oa likhato tse 100, 'me li hlatsuoa ka metsi a batang a tletseng, le bosoeu ba hlatsuoa. lesela la boka le lekanngoa, 'me ha boleng bo bosoeu bo le boholo ba W ke, ho molemo ho tlosa boka ba bokhoni ba surfactant.
Lebitso la surfactant | W boleng |
AEO-3 | W=67.42 |
AEO-5 | W=61.98 |
AEO-7 | W=53.25 |
AEO-9 | W=47.30 |
TX-10 | W=46.11 |
NP-8.6 | W=60.03 |
OP-10 | W=58.92 |
XL-90 | W=48.54 |
XP-90 | W=33.16 |
HO YA-7 | W=68.96 |
HO YA-9 | W=59.81 |
Mafura a mafura a methyl ester ethoxylate FMEE | W=77.43 |
Triethanolamine | W=49.79 |
Sesepa sa oli ea triethanolamine | W=56.31 |
Sesepa sa Net 6501 | W=32.78 |
Hlakola JFC | W=31.91 |
Fast T e phunyeletsa | W=18.90 |
Sesepa sa Net 209 | W=22.55 |
Sodium dodecylbenzene sulfonate LAS | W=34.17 |
Sodium dodecyl sulfate SDS | W=27.31 |
Sodium decyl-sulfonate --AOS | W=29.25 |
Sodium ea bobeli alkyl sulfonate SAS | W=30.87 |
Mafura a joala a ether sulfate AES | W=26.37 |
Mafura a joala ether carboxylate AEC | W=33.88 |
Clotrimazole(mokelikeli) | W=49.35 |
Phosphate ea lino tse tahang tse mafura | W=20.47 |
Phosphate esters ea mafura a joala ethers AEP | W=29.38 |
Nako ea poso: Mar-03-2022